a. boiling point
Boiling point. Characteristic properties are properties that can help uniquely identify a substance. Shape can change depending on how you cut a substance, and can be the same for pretty much any substance. Same with volume and weight, as they depend on the amount of the substance that you use. Only boiling point will be unique and vary depending on the substance. Some other characteristic properties include density, solubility, melting point, and magnetism.
A characteristic property of a substance is one that is unique to a particular substance. In this case, the boiling point is a unique property of every substance (and is thus your answer).
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