Guessing from the list I found of the 100 largest desalination plants, the countries with the biggest plans for getting water through desalination seem to be in the Middle East (which makes sense, as there’s not much fresh water there). Of them all, Saudi Arabia has the biggest plant (the Shuabia III, which produces 880,000 cubic meters per day), while the United Arab Emirates has the most plants overall (at 19). The USA also has a surprisingly large amount of desalination plants, at 17.
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