Naked mole rats have two genes that prevents the kind of cellular overcrowding that cancer cells need to proliferate. One, their first line of defense, is a gene called p27, which humans also have. When this gene fails (which it does, since humans have cancer) the naked mole rat relies on a second gene that only it seems to have, a gene called p16 that stops cellular overcrowding COLD. Basically, p16 makes it impossible for cancer cells to grow, which makes them immune.
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