Similar question have been ask before. Today Iceland is leading in the with in the clean energy race with up to 80% of their energy need being produced by renewable sources, mainly hydro and geothermal plants. But Iceland has a population of only 316 000 people.
Germany is can be the first major industrial country that can fully shift to renewable energy the soonest. At the current expanding rate of renewable energy they will become fully clean by 2050. And Germany has a population of 82 million.
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