As far as sheer number of solar panels is concerned, it’s difficult to tell for sure, but the largest single solar-powered building in the world is located in Dezhou, in Shandong Province, People’s Republic of China. The building contains offices, a convention center, a hotel and various R&D labs, all of which run on solar power. It is one of the largest office buildings in the world at over 800,000 square feet, and only 1% of the structure is steel, the vast majority of the rest being solar panels. It opened in December 2009. You can see a picture of it here:
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