The largest domestic breed of cat is called the Maine Coon Cat. Males can reach up to 13-18 pounds, females 9-12 pounds.
There is plenty of information on the Maine Coon here:
Also, the second-largest cat breed is the Ragdoll cat. This large cat was cross-bred in the 1960s, and were mainly bred for their friendly and dog-like personality. More information is at this website: http://www.buzzle.com/articles/information-on-ragdoll-cats.html
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