This website is a really user-friendly explanation of the ozone layer and hole. It has a lot of pictures to help even the duller crayons in the box better than I could explain it here in text.
The hole was discovered in 1985, and it has been attributed to man made compounds (mostly CFCs like those found in aerosols, but also halons, carbon tetrachloride, and methyl chloroform) which deplete the stratospheric ozone layer
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