There are a variety of ways. To kill off weeds, you can either use natural weed sprays or pull the weeds then cover up the area with a dark tarp to kill off any seeds left in the soil. From there, using bark or wood chips will prevent weeds from growing there. For more detailed instructions on killing weeds without harsh chemicals, see the links in the citations.
If you want to preserve plant species in close proximity with weeds, try removing weeds by digging or wacking it with a shovel. This hands-on method requires labor and constant maintenance, but offers a clean solution to killing/removing weeds.
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