Freon is a chemical in air conditioners so in order to not use freon you cant use your air conditioner.
Some (admittedly inconvenient) alternatives are:
Drive when it’s not so hot.
Roll down the windows.
Buy a sunscreen to put over windows you don’t look out of, and a large one for the windshield when your parked.
Why use chemicals to add to the pollution problem. Try an electric fan run by a solar cell of 15watts. They also make a portable Air Conditioner and exhaust ubit that pulls heat from the cabin. You can then drive in very hot weather and stay cool on arrival.
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