Well, google does have very green and energy efficient data centers. They have created an extremely streamlined electrical infastructure. Their Power Usage Effectiveness (PUE)is around 1.1 (with the lowest possible rating being 1.0). In addition, google has taken steps to use sustainable practices to run its data centers including employing water evaporation for cooling and implementing recycling projects. Hotmail is also a good green mail option because Microsoft data centers have plenty of eco-friendly features as well.
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