The U.S. Department of Energy has a Zero Energy Buildings Database (http://zeb.buildinggreen.com/) although none appear to be skyscrapers. This reference could expand greatly in the future as more buildings in the U.S. are built. Skyscrapers with net zero energy are found in China (1st link below) and Dubai (2nd link below). The first energy positive (creates more energy than it uses) office building is in Dijon, France (http://www.inhabitat.com/tag/net-zero/).
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