Here are some you might try: boiling water, vinegar, strong salt solutions, and lemon juice.
There is an organic and all natural weed killer called BurnOut that is also pet friendly. The boiling hot water and spraying trick is also very eco friendly but may also kill surrounding plants.
An effective eco-friendly weed killer is a salt and water solution. All you have to do is mix some salt and water in a spray water and spray on the weeds. Be careful with this solution though because it will ruin the fertility of the soil and nothing else will grow. Hot pepper and tobasco sauce on the weeds work too.
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